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叔胺的氮氧化物用活性試劑(如乙酸酐)處理,重排生成 N,N-二取代乙酰胺和醛的反應。此反應最常見的應用就是甲基叔胺脫甲基或者芐基叔胺脫芐基。
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圖片來源:https://cheminfographic.wordpress.com/2017/10/14/40-polonovski-reaction-1927/
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